- Salvation Army, Kemptville
- Sand Gravel & Aggregate, Kemptville
- Sandwich Shop Restaurants, Kemptville
- Secondary Schools, Kemptville
- Security Brokers & Dealers, Kemptville
- Seeds & Bulbs Wholesale & Growers, Kemptville
- Senior Citizens Housing, Kemptville
- Senior Citizens Service & Health Organizations, Kemptville
- Septic Systems Installation & Repair, Kemptville
- Septic Tank Pumping & Cleaning, Kemptville - Septic Systems
- Septic Tanks & Septic Systems Contractors, Kemptville - Installation, Repair, Service, Cleaning & Pumping Septic Tanks
- Sewage Septic Service, Kemptville
- Shoe Stores, Kemptville - Mens, Womens & Kids Shoes
- Shopping & Shopping Services, Kemptville
- Siding Contractors, Kemptville - Vinyl Siding, Wood, Metal & Aluminum Siding Contractors - Installation & Repair
- Signs, Kemptville
- Silos & Equipment, Kemptville
- Small Appliances, Kemptville
- Snow Removal Services, Kemptville - Snow Plow Service
- Social Clubs & Organizations, Kemptville
- Social Services & Welfare, Kemptville
- Societies & Foundation Associations, Kemptville
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- Sod & Sodding Service, Kemptville
- Solar Equipment, Kemptville
- Special Events Photographers, Kemptville
- Special Interest Schools Or Instruction, Kemptville
- Special Needs Transportation, Kemptville
- Speciality Food Stores, Kemptville
- Specialty Animal Services, Kemptville
- Specialty Stores, Kemptville
- Speech & Hearing Specialists, Kemptville
- Sporting & Recreational Camps, Kemptville
- Sporting Goods Equipment Rental, Kemptville
- Sporting Goods Stores, Kemptville
- Sportswear Manufacturers, Kemptville
- Sportswear Wholesale, Kemptville
- Staffing & Support Services, Kemptville
- Stocks & Bond Brokers, Kemptville
- Stress Management & Counseling, Kemptville
- Surveyor Services, Kemptville - Surveying Service
- Surveyors, Kemptville
- Swimming Pool, Sauna & Spa Contractors, Kemptville
- Swimming Pools Contractors, Kemptville - Install Inground - Above Ground Pools
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